Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex.
نویسندگان
چکیده
A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The Mn(IV)=O adduct is capable of activating C-H bonds by a H-atom transfer mechanism and is more reactive in this regard than most Mn(IV)=O species.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 49 47 شماره
صفحات -
تاریخ انتشار 2013